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991.
Bulk suspended particulate matter (SPM), chlorophyll a (Chl a), ignition loss, particulate organic carbon (POC), organic nitrogen, inorganic phosphorus (PIP), and organic phosphorus were investigated in the heavily eutrophic Arakawa River estuary, Japan. Chl a was high (approximately 35 microg l(-1)) in summer and low (approximately 6.7 microg l(-1)) in winter and autumn. POC from living phytoplankton accounted for approximately 34% and approximately 70% of total POC during low- and high-biomass seasons, respectively. During the low-biomass season, detrital POC distribution was conservative, and less reactive, land-derived materials mainly composed particulate organic materials (POM), but complex mixing of land-derived POM and autochthonous planktonic detritus caused nonconservative detrital POC behavior during the high-biomass season. PIP concentration in SPM decreased with increasing salinity, likely by desorption of soluble orthophosphate (ortho-P). The ortho-P released from SPM, 56% of the ortho-P input from the Arakawa River to the bay, was a significant potential source of biologically available phosphorus causing eutrophication of coastal environments.  相似文献   
992.
Twelve sediment samples collected from three transects of mangrove swamp of Deep Bay, Shenzhen, China, were determined for polynuclear aromatic hydrocarbons (PAHs). The total PAHs concentrations ranged from 237 to 726 ng g(-1) dry weight, and showed strong correlation with total organic carbon (TOC), clay content and Pb concentrations. The highest PAHs concentrations were found in the samples from mangrove sediments. Overall, PAHs in Deep Bay sediment were lower than those in other developed areas. The biological effect due to PAHs alone in Deep Bay is expected to be low, based on the comparisons of individual and total PAHs concentrations determined in the sediment with those in USEPA sediment quality guidelines. Four and five-ring compounds dominated the PAHs composition pattern profiles. Principal component analysis (PCA) was applied to further investigate the source of PAHs. The PAH sources of Deep Bay mangrove swamp were suggested to be primarily combustion of fossil fuel, especially leaded-gasoline exhaust.  相似文献   
993.
Common eiders nesting in the Baltic Sea are exposed to generally high levels of contaminants including potentially genotoxic polycyclic aromatic hydrocarbons and organochlorines. Blood samples were collected from eiders at eight sites in the Baltic Sea and two sites in the Beaufort Sea. DNA content variation was estimated using the flow cytometric method, and subsequently utilized as a biomarker of genetic damage. We observed no significant differences in genetic damage among populations within either the Baltic or Beaufort Seas. However, eider populations from the Baltic Sea had significantly elevated estimates of genetic damage compared to populations from the Beaufort Sea.  相似文献   
994.
Lysosomal membrane stability, the content of neutral lipids and lipofuscin as cellular biomarkers were measured in the digestive gland of mussels, Mytilus galloprovincialis Lam., during a one year survey at selected sites along the coast of the northern Adriatic. The ability of mussels to survive in air as a general physiological response was tested at the same sites. Annual changes of sea temperature, salinity, O(2) saturation, pH and chlorophyll a concentration were measured and the effects of these environmental factors on the biomarkers selected for this study were determined. Survival of mussels after aerial exposure was significantly (p < 0.05) reduced in mussels collected from the contaminated harbors of Pula and Rijeka compared to clean control sites. Lysosomal membrane stability of mussels from urban and industrial areas was also lower indicating exposure to different environmental contaminants. At the same sites, the content of neutral lipids and lipofuscin in digestive cells was significantly higher compared to the reference sites, suggesting alterations in lipid metabolism and contaminant-induced peroxidation of cell membranes. The greatest influence of natural environmental factors was observed for the aerial survival of mussels and the neutral lipids and lipofuscin content in the digestive gland, indicating that the annual cycles of biomarker responses should be well understood for a correct interpretation of biomonitoring results.  相似文献   
995.
Bacterial counts for total coliforms and E. coli in estuaries are normally orders of magnitude greater at the freshwater end than at the seaward end and tidal movements and variations in freshwater flows produce continual change in the freshwater/seawater mix--this causes the bacterial counts to vary greatly throughout the estuary and the complexity creates difficulty in appraising or assessing the bacterial counts (i.e. difficulties arise when deciding if the bacterial counts for estuarine water samples are within an acceptable range--relative to their corresponding salinities). The situation is further complicated in estuaries where sewage is discharged directly. Microbiological criteria and indices that can be used in a practical way to overcome these difficulties were developed. The procedure is summarised as follows: 1. Primary criteria are proposed for total coliform and for E. coli bacteria in the freshwater at the head of the estuary and in full seawater at the mouth of the estuary. 2. For estuarine or transitional waters (i.e. waters with salinity ranging from 0 per thousand to 35 per thousand), distinct criteria are calculated for each individual sample--with a separate criterion for total coliforms and for E. coli--the individual criteria are founded on the primary criteria and vary with salinity on a pro-rata or linear basis. 3. Finally, the Microbiological Index for each result is obtained by dividing the actual bacterial count by the corresponding criterion--the acceptable Index is then equal to 1--at any salinity (i.e. where the Index is <1 then the bacterial count complies with the criterion, and where the Index is >1 then the count breaches the criterion). The Index also indicates the extent of the compliance or non-compliance with the corresponding criteria. An example of the application of the Microbiological Index is also presented--including examples of graphs that demonstrate how microbiological data for estuarine waters can be summarised and presented.  相似文献   
996.
This study analysed the occurrence of genotypic shifts in laboratory populations of Hediste diversicolor (Polychaeta: Nereididae) exposed to copper stress. Specimens of H. diversicolor were collected at three sites, up to 10 km apart, in the estuarine area of the Pialassa lagoons (North Adriatic Sea, Italy) and were used in acute toxicity tests. Specimens were assigned to copper exposure (0.34 mg/l Cu2+) or control conditions. Each combination of Treatment and Site was replicated in two tanks containing 35 specimens of H. diversicolor. The genotypic structure of both dead and survived specimens was analysed by allozyme electrophoresis at six loci (ALD, FH, HBDH LDH, PGI, SDH). Under copper exposure, specimens with the genotypes ALD100/100 and PGI102/102 had significantly lower mortalities than other genotypes Results were consistent across the three sites, suggesting that, under laboratory conditions, effects of copper stress on H. diversicolor is related to individual genotypes at ALD and PGI loci.  相似文献   
997.
Surface water samples were collected from ten previously selected sites of the polluted Dil Deresi stream, during two field surveys, December 2001 and April 2002. All samples were analyzed using ICP-AES, and the concentrations of trace metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Pb, Sn and Zn) were determined. The results were compared with national and international water quality guidelines, as well as literature values reported for similar rivers. Factor analysis (FA) and a factor analysis-multiple regression (FA-MR) model were used for source apportionment and estimation of contributions from identified sources to the concentration of each parameter. By a varimax rotated factor analysis, four source types were identified as the paint industry; sewage, crustal and road traffic runoff for trace metals, explaining about 83% of the total variance. FA-MR results showed that predicted concentrations were calculated with uncertainties lower than 15%.  相似文献   
998.
An examination was made of the genetic variation with age in mangrove populations in two estuaries in south-east Australia, one contaminated, the other uncontaminated. Sediment nutrient and metal levels, and isozyme/allozyme complements were measured in three age-classes in four stands in each estuary, to identify site and intergenerational genetic composition, and influences of sediment contamination. Within each river, there were greater genetic distances among the age-classes than among sampling sites. A downstream gradient of genetic distance was found in the uncontaminated river, but not the contaminated one, where genetic distances seemed to reflect site-specific factors, though apparently not the present sediment metal or nutrient levels. It appears that genetic distances in the polluted river may reflect past fluctuations in pollution pressures. In both rivers, genetic distances indicate that the mangroves within one estuary form one population, with 'neighbourhood' differentiation.  相似文献   
999.
1000.
Simulating nonequilibrium transport of atrazine through saturated soil   总被引:5,自引:0,他引:5  
Mao M  Ren L 《Ground water》2004,42(4):500-508
Atrazine, an herbicide widely used for selective control of grassy weeds in the fields where maize is grown, is a potential ground water contaminant in China and, consequently, there is interest in predicting its mobility in agricultural soils. In this study, we determined the nonequilibrium transport characteristics of atrazine in Shahe soil (Beijing sandy loam) using the advection-dispersion equation, and using a sensitivity analysis, we evaluated the contribution of the uncertainty in a given input parameter to the overall uncertainty in model results. The asymmetrical shape and tailing of the atrazine breakthrough curve (BTC) showed that atrazine was subject to nonequilibrium transport. The observed atrazine BTC was best fitted by the chemical nonequilibrium model with a nonlinear least-squares optimization approach. Results from the sensitivity analysis indicated that the retardation factor was the most sensitive parameter. Considering the reliability of the estimated parameters, the best fit to the atrazine BTC was obtained by fixing the retardation factor based on the linear distribution coefficient, and by calculating the dispersion coefficient from the bromide BTC and the average pore water velocity from the measured data; nonequilibrium parameters were the only unknown parameters that were optimized. Model verification procedures were based on best-fit parameters optimized from one soil column experiment and applied to simulate the transport of atrazine in the duplicate experiment. The results showed there was good agreement between measured and simulated concentrations for atrazine leaching in the soil column.  相似文献   
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